Chirp excitation.

نویسنده

  • Navin Khaneja
چکیده

The paper describes the design of broadband chirp excitation pulses. We first develop a three stage model for understanding chirp excitation in NMR. We then show how a chirp π pulse can be used to refocus the phase of the chirp excitation pulse. The resulting magnetization still has some phase dispersion in it. We show how a combination of two chirp π pulses instead of one can be used to eliminate this dispersion, leaving behind a small residual phase dispersion. The excitation pulse sequence presented here allows exciting arbitrary large bandwidths without increasing the peak rf-amplitude. Experimental excitation profiles for the residual HDO signal in a sample of 99.5% D2O are displayed as a function of resonance offset. Although methods presented in this paper have appeared elsewhere, we present complete analytical treatment that elucidates the working of these methods.

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عنوان ژورنال:
  • Journal of magnetic resonance

دوره 282  شماره 

صفحات  -

تاریخ انتشار 2017